Dess-Martin Periodinane CAS 87413-09-0

Product Description:

Product Name: Dess-Martin periodinane CAS NO: 87413-09-0

Synonyms:

1,1,1-Triacetoxy-1,2-benziodoxole-IV-3(1H)-one;

1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M;

Dess-Martin periodinane,D M P, TAPI;

Chemical & Physical Properties:

Appearance: White crystalline powder

Assay :≥99.0%

Density: 1.362

Boiling Point: 40℃

Melting Point: 130-133℃

Flash Point: >105℃

Storage Condition: 0-6℃

Safety Information:

Safety Statements: S17-S23-S24/25-S36/37

WGK Germany: 3

RIDADR: UN 1593 6

Risk Statements: R40; R8

Hazard Code: Xn

Hazard Declaration: H272; H302 + H312 + H332; H315; H319; H335

Caution Statement: P220; P261; P280; P305 + P351 + P338

Symbol: GHS03, GHS07

Signal Word: Warning

Supplemental Hazard Statements: Risk of explosion if heated under confinement.

Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the reagent in 1983. It is based on IBX, but due to the acetate groups attached to the central iodine atom, DMP is much more reactive than IBX and is much more soluble in organic solvents.

If you are interested in our products or have any questions, please feel free to contact us!

Products under patent are offered for R & D purpose only. However, the final responsibility lies exclusively with the buyer.